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Preheat the oven to 350 degrees F. Grease a cast iron skillet and set off to the side.
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In a medium mixing bowl, whisk together the butter, agave, egg, buttermilk, chipotle, and pumpkin.
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In a separate large mixing bowl, combine the cornmeal, flour, salt, baking soda, and 1 ¾ cups cheese. Add the wet ingredients to the dry ingredients. Mix all ingredients until no dry bits are visible.
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Pour the batter into the cast iron skillet. Top with remaining cheese and a dash of paprika or chili powder. Bake in the oven for 20 minutes until the edges are slightly golden. Serve with big bowls of chili or eat solo!